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In my previous message
I used the expression "mythological science" and perhaps
I must give some explanation. I have the impression that, for more
than a century, the tendency in science has been to impose to Nature
myths of the sort "It is impossible for the event X to occur".
The event in question is usually difficult to test experimentally
so theoretical investigation is the only possible one. However the
negative form of the statement ("It is impossible...")
makes the logical difficulties enormous, although this is not seen
on the surface. For instance, one may try to connect the second
law in the form "Entropy never decreases" with some of
the Kelvin's versions, e.g. "No process is possible in which
a system absorbs heat from a reservoir, completely converts it into
work and returns to its initial state". Both are called second
laws but the connection is obscure (in fact it does not exist).
In addition, statements of this kind generate other myths - e.g.
"There have been many attempts to overthrow the principle but
all failed".
To give a somewhat different
example, let me mention another myth: "Catalysts (enzymes)
cannot shift the position of chemical equilibrium". This means
that, if a chemical reaction is at equilibrium and we add a catalyst,
the reaction will remain as it is - neither the forward nor the
backward reaction will be favored by the catalyst. In other words,
if the catalyst accelerates the forward reaction e.g. 97 times,
it must accelerate the backward reaction 97 times as well. No experimental
verification is reported in the literature, and yet the justification
is always the same: "No violation of the principle has ever
been detected". In fact, nearly all metabolic sequencies are
unidirectional – perhaps shifting the original equilibrium
and making the reaction unidirectional
is the main function of most enzymes.
Why are myths so persistent?
Because they make scientists' lives easier. Consider the following
principle: "No person can earn more money than he/she spends
for food, cloths and shelter" and imagine that the experimental
verification is difficult. What a nice and simple science would
emerge - no bank accounts and other complications. Unfortunately
analogous myths really operate in science.
Best regards,
Pentcho