I have received replies
to my earliest postings which convinced me that my activity is useful.
Let me suggest that the second law is not so sacred as it appears
- rather, it is an ordinary hypothesis that is easy to verify. Its
mythological status comes from the name "Perpetuum mobile of
the second kind" - it suggests that those who attempt a verification
are just as mad as those who try to produce work out of nothing.
Due to this threat, the second law has never been verified for more
complex systems (contrary to what textbooks say).
In fact, any system that,
under isothermal conditions, can produce two types of work, is suitable
for verification of the second law. Consider, for instance, a parallel-plate
constant-charge capacitor with vertical plates, suspended over a
pull of water. As we slowly draw the plates together, we can extract
work - the plates attract each other so, through a pulley, a weight
can be lifted. Then we slowly let the capacitor down and immerse
it into the pull. There we slowly draw the plates apart until the
initial distance between them is restored. The attraction in water
is about 80 times smaller, so the work we spend for drawing the
plates apart, in water, is 80 times smaller than the work we gain
as the plates are drawn together in air. In the final step, the
capacitor is taken out of the pull and the initial situation is
restored.
If we only consider the
net work extracted from the two movements of the plates - first
in air and then in water, we obviously have a great gain - much
more work gained in air than spent in water. The next question is:
at the expense of what is this net work done? There are two possible
hypotheses: A) At the expense of work spent by the operator as he
immerses and then withdraws the capacitor. B) At the expense of
heat absorbed from the surroundings. In the latter case the second
law is violated, in the former it is not. Why should thermodynamicists
forbidproblems of this kind to be even mentioned? The solution is
not easy, but I am sure that, once the problem is openly set, a
solution will be attempted by many people, even laymen.
Note that, if the hypothesis B is correct and the second law is
violated, the process is still too slow and unsuitable for industrial
application. That is the only problem with isothermal heat engines
- they are possible but slow and ineffective. Curiously, the first
living systems were isothermal heat engines - slowly and ineffectively
they "sucked" heat from the surroundings and converted
it into energy of chemical structures, until natural selection replaced
those mechanisms with much more powerful ones consuming external
agents rich in energy, e.g. photons. Ironically, Nature refused
to rely on the violation of the second law whereas man believes
this violation can resolve the energy crisis.
Best regards,
Pentcho Valev