The noble purpose of
SII to provide access to core ideas from science cannot be fulfilled
in some cases since the core ideas themselves are confused. Consider
chemical thermodynamics. Gibbs introduced the fundamental equation
dU = TdS - PdV + SUM
mu_i dn_i /1/
for a system IN EQUILIBRIUM,
and was wondering all along whether the entropy might have any meaning
at all for a system distant from equilibrium. Then someone found
it suitable to apply eq. /1/ to chemical reactions distant from
equilibrium, although he/she certainly did not know what dS might
mean in this case. In the absence of an ad hoc definition, the old
and only available definition
dS = dQrev/T /2/
filled the gap, although
Qrev plus "reaction distant from equilibrium" certainly
form an oxymoron. As a result, although the name "equilibrium
thermodynamics" has been preserved, this science essentially
deals with reactions distant from equilibrium and the original oxymoron
has taken multiple forms, to student's horror (let alone the general
public). In contrast, the so-called non-equilibrium thermodynamics
says that reactions distant from equilibrium are difficult to deal
with, and reduces its activity to systems very close to equilibrium
where the Onsager's relations can be applied. Too much absurdity
is paralysing so things are not going to change.
Pentcho Valev