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Hi. I am a Bulgarian
researcher interested in the foundations of thermodynamics, and
I wonder if this list would welcome challenges that usually meet
hostility. There is a conference on the second law in San Diego
this summer and I am going to participate, but why not an e-mail
discussion as well. Please tell me if you see any difference between
the following two Kelvin's versions:
K1: No process is possible
in which the only result is absorption of heat from a reservoir
and its complete conversion into work.
K2: No process is possible in which a system absorbs a heat from
a reservoir, completely converts it into work and returns to its
initial state.
In order to find the
difference, please think of a creature belonging to the surroundings
(I call it "operator") that e.g. sets the heat engine
on and off, switches to a different work production etc. and UNDERGOES
CHANGES IN THE PROCESS. So, for isothermal conditions, the two versions
take the forms:
K1: In the absence of
an operator, cyclical isothermal conversion of heat into work is
impossible.
K2: Even in the presence of an operator, cyclical isothermal conversion
of heat into work is impossible.
Clearly, K2 is more restrictive
than K1, and it may turn out that K1 is correct whereas K 2 is not.
At the San Diego conference, I am going to develop further the problem:
K1 is related to "Entropy never decreases" whereas K2
is related to "Entropy is a state function".
Is anybody interested
in such problems?
Best regards,
Pentcho Valev
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